PROFIL PRACOWNIKA: Dariusz Guziejewski
dr hab. Dariusz Guziejewski
e-mail: dariusz.guziejewski@chemia.uni.lodz.pl
www: https://www.chemia.uni.lodz.pl/zaklad-analizy-instrumentalnej/pracownicy
SCIENTIFIC AND SOCIAL MEDIA PROFILES
POSITION DESCRIPTION
electroanalysis of selected biologically active substances;
modeling of selected electrode processes usinge SWV technique;
study of the kinetics of electrode reactions;
design novel electrocatalytic materials;
development and characterization of novel electrochemical measurement techniques
I consider the most important research achievements to be:
1. Explanation of the phenomenon of splitting of the analytical (resulting) signal, as a result of changes in its components, caused by different values of the potential pulse amplitude in square-wave voltammetry (SWV).
2. Proposing an original method for performing electrokinetic studies for various mechanisms of electrode processes using the SWV technique, with an adjustable value of the potential pulse amplitude, based on:
a) analysis of the relative position of the SWV spectrum component signals, in the case of interpretation of standard SWV voltammograms and voltammograms in which the potential was corrected (potential compensation to the value corresponding to the current sampling moment);
b) introduction of a new term to voltammetry, "quasi-reversible maximum based on amplitude", which is justified by the interpretation of SWV electrochemical spectra. 3. Proposing, developing and introducing an innovative series of research techniques into voltammetry, based on electrochemical Faradaic spectroscopy and its variants: multi-frequency, multi-amplitude and multi-amplitude-frequency. 4. Proposing for analytical purposes the principle of extending the range of pulse amplitude values in the SWV square wave technique based on the above-mentioned potential correction.
BIOGRAPHICAL NOTE
Since October 2006, PhD student at the Department of Instrumental Analysis.
Since October 2007, assistant at the Department of Instrumental Analysis.
Since 2014, assistant professor at the Department of Instrumental Analysis.
INTERESTS
Publications:
- V. Mirceski, D. Guziejewski, R. Gulaboski; Genuine Anodic and Cathodic Current Components in Cyclic Voltammetry; Scientific Reports, 2024, 14, 17314.
- N. Ullah, D. Guziejewski, V. Mirceski; "Mechanistic aspect of copper selenide as an electrocatalyst for the detection of hydrogen peroxide in gaseous phase"; International Journal of Hydrogen Energy, 2024, 74 , 238-245.
- Sami Ullah, Nabi Ullah, Syed Shaheen Shah, Dariusz Guziejewski, Firoz Khan, Iltaf Khan, ,Aziz Ahmad, Muhammad Saeed, Sikandar Khan, Fazal Mabood; "Theoretical and experimental progress in photothermal catalysis for sustainable energy and environmental protection: Key problems and strategies towards commercialization";
Renewable and Sustainable Energy Reviews, 2024, 201 , 114615. - B. Barton, N. Ullah, K. Koszelska, S. Smarzewska, W. Ciesielski, D. Guziejewski; "Reviewing neonicotinoids detection with electroanalytical methods";
Environmental Science and Pollution Research, 2024, 31, 37923–37942. - N. Ullah, D. Guziejewski, K. Koszelska, S. Smarzewska, M. Małecka, K. Ranoszek-Soliwoda, J. Grobelny;
"Chrysanthenum-Flowers-Like Bimetal Oxide Based Electrocatalyst for Methanol Oxidation Reaction";
Energy Technology, 2024, 12 (7), 2400075. - N. Ullah, S. Khan, B. Barton, D. Guziejewski, S. Smarzewska, K. Koszelska, V. Mirceski;
"A mini review on topographical and structural insight of metal carbides for electrocatalytic hydrogen peroxide detection";
Microchemical Journal, 2024, 200, 109961. - Nabi Ullah, Dariusz Guziejewski, Asim Mahmood, Sami Ullah, Sikandar Khan, Shahid Hussain, Muhammad Imran;
"Three-dimensionally arranged NiSe2 nanosheets as an efficient electrocatalyst for methanol electrooxidation reaction";
Energy Technology, 2024, 2400390. - N. Ullah, D. Guziejewski, B. Barton, V. Mirceski;
"Electrocatalytic reduction of hydrogen peroxide in solution in the presence of polyacrylic acid and copper ions: Application for gaseous hydrogen peroxide detection";
Journal of Electroanalytical Chemistry, 2023, 951, 117918. - N. Ullah, S. Chmiel, D. Guziejewski, S. Khan, S. Hussain, M. Malecka;
"Copper Selenide Nanobelts an Electrocatalyst for Methanol Electro-Oxidation Reaction";
Ionics, 2023, 29, 5363–5368. - N. Ullah, D. Guziejewski, K. Koszelska, M. Malecka, K. Ranoszek-Soliwoda, J. Grobelny, V. Mirceski;
"Formation mechanism of macroporous Cu/CuSe and its application as electrocatalyst for methanol oxidation reaction";
Ionics, 2023, 29, 4835-4840. - D. Guziejewski, S. Smarzewska, V. Mirceski;
"Analytical aspects of novel techniques derived from square-wave voltammetry";
Journal of the Electrochemical Society, 2023, 170 (6), 066503. - V. Ivanovski, N. Festinger, R. Karpowicz, P. Tokarz, K. Spilarewicz, D. Guziejewski, S. Smarzewska;
"Tailoring electrochemical activity of acemetacin with electrocatalytic properties of graphene derivatives";
Journal of the Electrochemical Society, 2023, 170, 057503. - S. Smarzewska, D. Guziejewski, N. Ullah, K. Koszelska ;
"Electrochemical evaluation of free radical scavenging activity of sesamol";
Journal of the Electrochemical Society, 2023, 170, 055502. - Nabi Ullah, Dariusz Guziejewski;
"Formation of tungsten doped molybdenum selenide electrocatalyst for methanol oxidation reaction";
Ionics, 2023, 29, 2523-2527. - Nabi Ullah, Dariusz Guziejewski , Aihua Yuan, Sayyar Ali Shah;
"Recent advancement and structural engineering in transition metal dichalcogenides for alkali metal ions batteries";
Materials, 2023, 16, 2559. - N. Ullah, S. Ullah, S. Khan, D. Guziejewski, V. Mirceski;
"A review: Metal-organic framework based electrocatalysts for methanol electro-oxidation reaction"; `
International Journal of Hydrogen Energy, 2023, 48 (9), 3340-3354. - N. Festinger, A. Kisielewska, B. Burnat, K. Ranoszek-Soliwoda, J. Grobelny, K. Koszelska, D. Guziejewski, S. Smarzewska;
"The influence of graphene oxide composition on properties of surface-modified metal electrodes";
Materials, 2022, 15, 7684. - D. Guziejewski, L. Stojanov, Z. Zwierzak, R. G. Compton, V. Mirceski;
"Electrode kinetics from a single experiment: Multi-amplitude analysis in square-wave chronoamperometry";
Physical Chemistry Chemical Physics, 2022, 24, 24419-24428. - R. Metelka, P. Vlasakova, S.Smarzewska, D. Guziejewski, M. Vlcek, M. Sys;
"Screen-printed carbon electrodes with macroporous copper film for enhanced amperometric sensing of saccharides";
Sensors, 2022, 22 (9), 3466. - E. Skowron, K. Spilarewicz-Stanek, D. Guziejewski, K. Koszelska, R. Metelka, S. Smarzewska;
"Analytical performance of clay paste electrode and graphene paste electrode - comparative study";
Molecules, 2022, 27 (7), 2037. - D. Guziejewski, L. Stojanov, R. Gulaboski, V. Mirceski;
"Reversible and quasireversible electron transfer under conditions of differential square-wave voltammetry";
J. Phys. Chem. C, 2022, 126 (12), 5584-5591. - N. Festinger, K. Spilarewicz-Stanek, K. Borowczyk, D. Guziejewski, S. Smarzewska;
"Highly sensitive determination of tenofovir in pharmaceutical formulations and patients urine - comparative electroanalytical studies using different sensing methods";
Molecules, 2022, 27 (6), 1992. - V. Ivanovski, I. Piwonski, D. Guziejewski, T.G. Mayerhofer;
"Detection of siloxane thin films on glass substrate using IR ratio-reflectance spectrum";
Spectrochim. Acta A Mol. Biomol. Spectrosc., 2022, 271, 120893. - L. Stojanov, D. Guziejewski, M. Puiu, C. Bala, V. Mirceski;
"Multi-frequency analysis in a single square-wave chronoamperometric experiment";
Electrochem. Commun., 2021, 124, 106943. - D. Guziejewski;
"Electrode mechanisms with coupled chemical reaction - amplitude effect in square-wave voltammetry";
Journal of Electroanalytical Chemistry, 2020, 114186. - V. Mirceski, D. Guziejewski, L. Stojanov, R. Gulaboski;
"Differential square-wave voltammetry";
Anal. Chem., (2019), 91 (23), 14904-14910. - P. Bałczewski, E. Kowalska, J. Skalik, E. Różycka-Sokołowska, K. Owsianik, M. Koprowski, B. Marciniak, D. Guziejewski, W. Ciesielski;
"Mono-aryl/alkythio-substituted (hetero)acenes of exceptional thermal and photochemical stability via thio-Friedel Crafts/Bradsher cyclization reaction";
Chem. Eur. J., (2019), 25 (62), 14148-14161. - K. Morawska, K. Jedlińska, S. Smarzewska, R. Metelka, W. Ciesielski, D. Guziejewski;
"Analysis and DNA interaction of the profluralin herbicide";
Environmental Chemistry Letters, (2019), 17 (3), 1359-1365. - D. Guziejewski;
"Square-wave amplitude effect in cathodic and anodic stripping square-wave voltammetry";
Electroanalysis, (2019), 31 (2), 231-238. - S. Smarzewska, E. Miękoś, D. Guziejewski, M. Zieliński, B. Burnat,
"Graphene oxide activation with a constant magnetic field";
Anal. Chim. Acta, (2018), 1011, 35-39. - D. Guziejewski, K. Morawska, T. Popławski, R. Metelka, W. Ciesielski, S. Smarzewska;
"Lactofen - electrochemical sensing and interaction with dsDNA";
Electroanalysis, (2018), 30 (1), 94-100. - D. Jadresko, D. Guziejewski, V. Mirceski;
"Electrochemical Faradaic Spectroscopy";
ChemElectroChem, 5, 187-194 (2018) - S. Smarzewska, D. Guziejewski, A. Leniart, W. Ciesielski;
"Nanomaterials vs Amalgam in Electroanalysis: Comparative Electrochemical Studies of Lamotrigine";
J. Electrochem. Soc., 164 (7), B321-B329 (2017) - S. Smarzewska, A. Jasińska, W. Ciesielski, D. Guziejewski;
"First electroanalytical studies of profluralin with square wave voltammetry using glassy carbon electrode";
Electroanalysis, 29 (1), 244-248 (2017) - D. Guziejewski, S. Smarzewska, R. Metelka, A. Nosal-Wiercińska, W. Ciesielski;
"Improved electroanalytical characteristics for flumetralin determination in the presence of surface active compound";
Monatsh. Chem., 148 (3), 555-562 (2017) - S. Smarzewska, N. Festinger, M. Skowron, D. Guziejewski, R. Metelka, M. Brycht, W. Ciesielski;
"Voltammetric analysis of disulfiram in pharmaceuticals with a cyclic renewable silver amalgam film electrode";
Turk. J. Chem., 41 (1), 116-124 (2017) - A. Nosal-Wiercińska, M. Wiśniewska, M. Grochowski, W. Kaliszczak, S. Skrzypek, M. Brycht, D. Guziejewski, W. Franus;
"The effect of homocysteine and homocystine protonation on double layer parameters at the electrode/chlorates(VII) interface";
Adsorption Science and Technology, 35 (5-6), 396-402 (2017) - S. Smarzewska, R. Metelka, N. Festinger, D. Guziejewski, W. Ciesielski;
"Comparative study on electroanalysis of fenthion using silver amalgam film electrode and glassy carbon electrode modified with reduced graphene oxide";
Electroanalysis, 29 (4), 1154-1160 (2017) - D. Guziejewski, A. Nosal-Wiercinska, S. Skrzypek, W. Ciesielski, S. Smarzewska;
"First electrochemical method of nitrothal-isopropyl determination in water samples";
J. Chem., (2016), Article ID 6045347, 6 pages - V. Mirceski, D. Guziejewski, M. Bozem, I. Bogeski;
"Characterizing electrode reactions by multisampling the current in square-wave voltammetry";
Electrochim. Acta, 213, 520-528 (2016) - D. Guziejewski, S. Smarzewska, M. Skowron, W. Ciesielski, A. Nosal-Wiercinska, S. Skrzypek;
"Rapid and sensitive voltammetric determination of aclonifen in water samples";
Acta Chimica Slovenica, 63 (1), 1-7 (2016) - V. Mirceski, S. Smarzewska, D. Guziejewski;
"Measuring the electrode kinetics of vitamin B2 at a constant time window of a square wave voltammetric experiment";
Electroanalysis, 28 (2), 385-393 (2016) - P. Bałczewski, J. Skalik, P. Uznański, D. Guziejewski, W. Ciesielski;
"Use of Isomeric, Aromatic Dialdehydes in Synthesis of Photoactive, Positional Isomers of Higher Analogs of o-Bromo(hetero)acenaldehydes";
RSC Advances, 5 (31), 24700-24704 (2015) - V. Mirceski, D. Guziejewski, R. Gulaboski;
"Electrode kinetics from a single square-wave voltammogram";
Macedonian Journal of Chemistry and Chemical Engineering, 34(1), 181-188 (2015) - A. Nosal-Wiercińska, M. Grochowski, M. Wiśniewska, K. Tyszczuk-Rotko, S. Skrzypek, M. Brycht, D. Guziejewski;
"The Influence of Protonation on the Electroreduction of Bi(III) Ions in Chlorates (VII) Solutions of Different Water Activity";
Electrocatalysis, 6 (3), 315-321 (2015) - D. Guziejewski, V. Mirceski, D. Jadresko;
"Measuring the electrode kinetics of surface confined electrode reactions at a constant scan rate";
Electroanalysis, 27(1), 67-73 (2015) - M. Brycht, S. Skrzypek, J. Robak, V. Guzsvany, O. Vajdle, J. Zbiljic, A. Nosal-Wiercińska, D. Guziejewski, G. Andrijewski;
"Ultra trace level determination of fenoxanil by highly sensitive square wave adsorptive stripping voltammetry in real samples with a renewable silver amalgam film electrode";
J. Electroanal. Chem., 738, 69-76 (2015) - M. Brycht, S. Skrzypek, A. Nosal-Wiercińska, S. Smarzewska, D. Guziejewski, W. Ciesielski, B. Burnat, A. Leniart;
"The new application of renewable silver amalgam film electrode for the electrochemical reduction of nitrile, cyazofamid, and its voltammetric determination in the real samples and in a commercial formulation";
Electrochimica Acta, 134, 302-308 (2014) - S. Smarzewska, D. Guziejewski, M. Skowron, S. Skrzypek, W. Ciesielski;
"Voltammetric behavior and quantitative determination of ambazone in urine and a pharmaceutical formulation";
Central European Journal of Chemistry, 12(12), 1239-1245 (2014) - D. Guziejewski, M. Brycht, A. Nosal-Wiercińska, S. Smarzewska, W. Ciesielski, S. Skrzypek;
"Electrochemical study of the fungicide acibenzolar-s-methyl and its voltammetric determination in environmental samples";
J. Environ. Sci. Health B, 49(8), 550-556 (2014) - S. Smarzewska, R. Metelka, D. Guziejewski, M. Skowron, S. Skrzypek, M. Brycht, W. Ciesielski;
"Voltammetric behaviour and quantitative determination of pesticide iminoctadine";
Anal. Methods, 6, 1884 - 1889, (2014) - V. Mirceski, D. Guziejewski, K. Lisichkov;
"Electrode kinetic measurements with square-wave voltammetry at a constant scan rate";
Electrochim. Acta, 114, 667-673, (2013) - V. Mirceski, E. Laborda, D. Guziejewski, R. G. Compton;
"New Approach to Electrode Kinetic Measurements in Square-Wave Voltammetry. Amplitude-Based Quasireversible Maximum";
Anal. Chem., 85 (11), 5586-5594, (2013) - A. Nosal-Wiercińska, M. Grochowski, S. Skrzypek, D. Guziejewski;
"Application of the catalytic properties of methionine to the determination of Bi(III) as well in the presence of Cu(II) ions at low levels by square wave voltammetry";
Desalination and Water Treatment, 51 (7-9), 1700-1704, (2013) - D. Guziejewski, M. Brycht, S. Skrzypek, A. Nosal-Wiercińska, W. Ciesielski;
"Voltammetric Determination of Acibenzolar S-Methyl Using a Renewable Silver Amalgam Film Electrode";
Electroanalysis, 24 (12), 2303-2308, (2012) - D. Guziejewski, S. Skrzypek, W. Ciesielski;
"Square Wave Adsorptive Stripping Voltammetric Determination of Diazinon in its Insecticidal Formulations";
Environ. Monit. Assess., 184 (11), 6575-6582, (2012) - D. Guziejewski, S. Skrzypek, W. Ciesielski;
"Application of Catalytic Hydrogen Evolution in the Presence of Neonicotinoid Insecticide Clothianidin";
Food Anal. Methods, 5 (3), 373-380, (2012) - S. Skrzypek, V. Mirceski, S. Smarzewska, D. Guziejewski, W. Ciesielski;
"Voltammetric Study of 2-Guanidinobenzimidazole: Electrode Mechanism and Determination at Mercury Electrode";
Collect. Czech. Chem. Commun., 76 (12), 1699-1715 (2011) - V. Mirceski, D. Guziejewski, W. Ciesielski;
"Theoretical Treatment of a Cathodic Stripping Mechanism of an Insoluble Salt Coupled with a Chemical Reaction in Conditions of Square Wave Voltammetry. Application to 6-Mercaptopurine-9-D-Riboside in the Presence of Ni(II)";
Electroanalysis, 23 (6), 1365-1375 (2011) - D. Guziejewski, S. Skrzypek, A. Łuczak, W. Ciesielski;
"Cathodic Stripping Voltammetry of Clothianidin: Application to Environmental Studies";
Collect. Czech. Chem. Commun., 76 (2), 131-142 (2011) - V. Mirceski, D. Guziejewski, S. Skrzypek, W. Ciesielski;
"Electrochemical Study of the Pesticide Methidathion at a Mercury Electrode Under Cathodic Stripping Mode";
Croat. Chem. Acta, 83(2), 121-126 (2010) - F. G. Banica, D. Guziejewski, S. Skrzypek, W. Ciesielski, D. Kazmierczak;
"Effect of Basic Amino Acids on Nickel Ion Reduction at a Mercury Electrode";
Electroanalysis, 21, 1711-1718 (2009)
Patent applications:
- Dariusz Guziejewski, Nabi Ullah, Sylwia Smarzewska; Sposob otrzymywania selenku niklowo-kobaltowego NiCo2Se4; zgłoszenie nr P.443672 z dn. 2023-02-02;
- Dariusz Guziejewski, Valentin Mirceski, Sylwia Smarzewska; Sposob zmiany wartosci potencjalu w trakcie pomiaru elektrochemicznego; zgłoszenie nr P.444085 z dn. 2023-03-15; rozszerzenie europejskie "Method of changing the potential value during an electrochemical measurement" nr EP24163510 z dn. 14.03.2024.
- Dariusz Guziejewski, Sylwia Smarzewska; Korpus elektrody dyskowej do pomiarów zwielokrotnionych; zgłoszenie nr P.444330 z dn. 2023-04-06; rozszerzenie międzynarodowe "A multiple disc electrode holder" nr PCT/IB2024/052229 z dn. 07.03.2024.
- Sylwia Smarzewska, Dariusz Guziejewski, Nabi Ullah, Kamila Koszelska, Monika Skowron-Jaskolska, Ewa Miekos, Marek Zielinski; Korpus elektrodowy do pomiarów elektrochemicznych; zgłoszenie nr P.444434 z dn. 2023-04-17;
- Sylwia Smarzewska, Dariusz Guziejewski, Grzegorz Smarzewski; Korpus multielektrody pastowej do usrednionych pomiarow jednoczesnych; zgłoszenie nr P.444974 z dn. 2023-05-24; rozszerzenie europejskie "Paste multielectrode body for simultaneous averaging measurements" nr EP24175808 z dn. 14.05.2024.
- Sylwia Smarzewska, Kamila Koszelska, Dariusz Guziejewski, Ewa Miękoś, Michał Świderski, Monika Wypych, Nabi Ullah; Sposób oznaczania tymochinonu w roztworach wodnych lub w roztworach na bazie rozpuszczalników rozpuszczalnych w wodzie; zgłoszenie nr P.445674 z dn. 2023-07-25;
- Dariusz Guziejewski; Sposób rejestracji natężenia prądu w trakcie pomiaru elektrochemicznego; zgłoszenie nr P.446864 z dn. 2023-11-27;
- Dariusz Guziejewski, Valentin Mirceski, Sylwia Smarzewska, Nabi Ullah, Kamila Koszelska, Monika Skowron-Jaskólska; Sposób prowadzenia analizy woltamperometrycznej z użyciem potencjału o kształcie fali prostokątnej w trakcie pomiaru elektrochemicznego ; zgłoszenie nr P.446960 z dn. 2023-12-01;
- Valentin Mirceski, Dariusz Guziejewski, Sylwia Smarzewska, Kamila Koszelska, Nabi Ullah; Sposób otrzymywania kompozytu drewno-metal ; zgłoszenie nr P.448379 z dn. 2024-04-22;
- Sylwia Smarzewska, Kamila Koszelska, Dariusz Guziejewski; Sposób oznaczania 2-metylo-5-izopropylocykloheks-2,5-dien-1,4-dionu w suplementach diety i olejach spożywczych; zgłoszenie nr P.448960 z dn. 2024-06-25;
ACHIEVEMENTS
Scientific achievements in the field of electrochemistry and electroanalytics should be classified in the discipline: chemical sciences; fields: exact and natural sciences.
Dr. hab. Dariusz Guziejewski is interested in a wide range of topics in the field of electrochemistry, which include:
Chemical electroanalysis of selected biologically active substances: This area of research focuses on the development of new voltammetric methods that can be used to detect and quantify substances. He studies various electrochemical techniques, such as square-wave amperometry, square-wave differential voltammetry or variants of analysis using the SWV technique, in order to develop sensitive and selective methods for detecting these substances.
Modeling selected electrode processes in the SWV technique and related ones: As part of this research interest, he deals with the simulation of electrode processes using numerical models, especially in the context of using the square-wave voltammetry technique. By modeling these processes, Dr. Hab. Guziejewski aims to better understand the mechanisms of electrode reactions and optimize measurement conditions to obtain the highest possible sensitivity and precision of measurements.
Study of electrode reaction kinetics: Focuses on studying the rate and mechanisms of electrode reactions, and as part of the demonstrated scientific achievement in the habilitation procedure, he presented the nature and usefulness of the effect of the amplitude of a square wave in the SWV technique and not only. This allows him to estimate the kinetics of the electrode reaction based on the above-mentioned parameter without the need to change the time frame of the experiment. In this way, analysis methods for selected reaction mechanisms were developed. Within this subject, two projects financed by the National Science Center were implemented, which enabled the modernization of the scientific equipment of the Department and contributed to the expansion of the topics of the conducted research.
Study of new electrocatalytic materials: Deals with the search for new electrocatalytic materials that can be used to increase the efficiency and selectivity of various electrode reactions, such as the determination of hydrogen peroxide, but also the oxidation of methanol, the reduction of carbon dioxide or the water splitting reaction. These studies include synthesis, characterization and testing of electrocatalyst properties, also using non-electrochemical techniques, as a result of which a patent solution for a solvothermal method of nickel-cadmium selenide synthesis was filed.
Development and characterization of new electrochemical measurement techniques: It also contributes to the development and characterization of new electrochemical measurement techniques, deals with, among others, designing and developing new measurement protocols and assessing their effectiveness and applicability. The aim is to create more advanced tools and techniques enabling more detailed study of electrode processes and their practical application, as a result of which 3 patent applications were filed.
CONTACT DETAILS AND OFFICE HOURS
phone: 42-635-54-80
e-mail: dariusz.guziejewski@chemia.uni.lodz.pl
Pomorska 163/165 room: ZAI, Pomorska 163, p.7 90-236 Łódź
wednesday: 13:00-15:00